Fat32Formatter is freeware and made by TOKIWA to format drive larger than 32GB to FAT32.This software has a simple and instructive UI, can set and delete partitions as well, it is compatible with Windows2000/XP/Vista32 and can walk around the OS restriction.
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I also found another tool called NTFS to FAT32 Converter. Between the two tools, which one is better? :(